Semiconductor nanostructures via electrodeposition from ionic liquids*

نویسندگان

  • Rihab Al-Salman
  • Xiangdong Meng
  • Jiupeng Zhao
  • Yao Li
  • Ulrich Kynast
  • Marina M. Lezhnina
  • Frank Endres
چکیده

The fascinating properties of ionic liquids make it possible to synthesize semiconductor nanostructures via a simple and low-cost electrochemical pathway. The present paper summarizes our recent work on the synthesis of Si, Ge, and SixGe1–x nanostructures from ionic liquids: thin films, nanowires and photonic crystals. We also introduce our first results on the template-assisted electrodeposition of SixGe1–x photonic crystals from 1-ethyl-3methylimidazolium bis(trifluoromethylsulfonyl)amide ([EMIm]Tf2N) ionic liquid, and some optical measurements on the previously prepared Ge photonic crystals. Our results confirm that electrochemistry in ionic liquids is excellently suited to the synthesis of high-quality semiconductor nanostructures.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis and characterization of controlled metal nanostructures for electrochemical applications

Aalto University, P.O. Box 11000, FI-00076 Aalto www.aalto.fi Author Nguyet Doan Name of the doctoral dissertation Synthesis and characterization of controlled metal nanostructures for electrochemical applications Publisher School of Chemical Technology Unit Department of Chemistry Series Aalto University publication series DOCTORAL DISSERTATIONS 177/2016 Field of research Physical Chemistry Ma...

متن کامل

Electrochemical and spectroscopic study of Zn(ii) coordination and Zn electrodeposition in three ionic liquids with the trifluoromethylsulfonate anion, different imidazolium ions and their mixtures with water.

In this paper we report on the use of three ionic liquids, 1-methylimidazolium trifluoromethylsulfonate ([MIm]TfO), 1-ethyl-3-methylimidazolium trifluoromethylsulfonate ([EMIm]TfO) and 1-ethyl-2,3-dimethylimidazolium trifluoromethylsulfonate ([EMMIm]TfO) containing zinc trifluoromethylsulfonate as electrolytes for zinc electrodeposition. By varying the cations from [MIm](+)via [EMIm](+) to [EMM...

متن کامل

Electrofinishing of metals using eutectic based ionic liquids

Ionic liquids are molten salts that have low melting points. This review concentrates upon eutectic mixtures of quaternary ammonium salts and metal salts (usually halides). These so-called eutectic based ionic liquids can be used for the electrodeposition and dissolution of a wide range of metals and alloys. The review highlights the technological challenges involved in the application of ionic...

متن کامل

Imidazolium-based Ionic liquids on Morphology and Optical Properties of ZnO Nanostructures

ZnO nanostructures have been synthesized by a simple reflux method, using different ionic liquids, such as 1-benzyl-3-methylimidazolium bromide ([BzMIM][Br]), 1,1'-(1,4 phenylenebis (methylene)) bis (3-methyl-1H-imidazol-3-ium) bromide ([MM-1,4-DBzIM2][Br]2) and 1-phenacyl-3-methylimidazolium bromide ([PMIM][Br]), with different amount of sodium hydroxide in water. Als...

متن کامل

Electrodeposition of germanium at elevated temperatures and pressures from ionic liquids.

The electrodeposition of germanium at elevated temperatures up to 180 °C and pressures was studied from the ionic liquids 1-butyl-1-methylpyrrolidinium dicyanamide and 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide containing [GeCl4(BuIm)2] (where BuIm = 1-butylimidazole) or GeCl4. Cyclic voltammetry (CV), electrochemical quartz crystal microbalance (EQCM), rotating ring-disk e...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2010